EC / List no.: 229-194-7
CAS no.: 6425-39-4
Mol. formula: C12H24N2O3
DABCO DMDEE is an amine blowing catalyst.
DABCO DMDEE is used in rigid foam sealant systems as well as for flexible slabstock foams.
DABCO DMDEE is suitable for processing by extrusion blow molding.
DABCO DMDEE is an amine catalyst that is isocyanate stable.
DABCO DMDEE is used in one component moisture cured applications in CASE.
DABCO DMDEE is a tertiary amine catalyst for the production of polyurethane foam, especially suitable for the manufacturing of polyester polyurethane foams or for the preparation of one component foams.
Physical Properties of DABCO DMDEE:
Appearance:clear, yellowish liquid with, typical amine odor
Purity: ≥ 99 %
Water Content: ≤ 0.5 %
Instructions for Storage:
The solidification point of DABCO DMDEE is below -20 °C, i. e. storage temperatures fluctuating around 0 °C do not cause any deterioration of the material.
Nevertheless DABCO DMDEE is recommended to bring the material to room temperature before the material is used.
For DABCO DMDEE we guarantee a shelf life of at least 12 months upon delivery under the condition, that it is stored in factory-packed containers and protected against extreme weather conditions, particularly against heat and moisture.
After a prolonged storage of DABCO DMDEE the color of the product may change to slightly yellow or brownish, however, the catalytic activity remains unchanged.
Applications of DABCO DMDEE:
For many years DABCO DMDEE has been known in the polyurethane foaming industry as a well approved catalyst, specially supporting the water / isocyanate reaction.
DABCO DMDEE is mainly used in the production of foams, e.g. polyester polyurethane foams or one component foams where on one hand the so-called "gas reaction" is promoted, but on the other hand the influence on the so-called "cross-linking reaction" is minor.
Due to the almost not existing gelling / cross-linking activity, DABCO DMDEE provides a very long shelf life when used in prepolymers.
Safety Instructions of DABCO DMDEE:
DABCO DMDEE should be handled only in well ventilated rooms.
Always wear safety goggles and gloves when working with DABCO DMDEE, in order to prevent any contact.
If in spite of all precaution measures skin contact did occur, wash the affected area thoroughly with water and soap.
After eye contact flush immediately with plenty of water and seek for medical advise.
Morpholine diethyl ether is used as a one-component polyurethane system (such as one-component polyurethane sealant, one-component polyurethane foam, one-component polyurethane.
The catalyst (or curing agent) in grouting materials, etc.).
Since one-component polyurethane prepolymer requires long-term storage stability, bismorpholine diethyl ether plays a key role in the stability and polymerization of polyurethane prepolymer.
The product quality puts forward extremely high requirements.
Alias: 2,2-bismorpholinyl diethyl ether, dimorpholinyl diethyl ether, bis(2,2-morpholinoethyl) ether.
Abbreviation: DABCO DMDEE, bismorpholinyl diethyl ether, CAS 6425-39-4, catalyst DABCO DMDEE, polyurethane catalyst DABCO DMDEE, foaming catalyst DABCO DMDEE DABCO DMDEE, Foam catalyst DABCO DMDEE, polyurethane foam catalyst DABCO DMDEE
English name: 2,2-dimorpholinodiethylether;bis(2,2-morpholinoethyl)ether.
Molecular formula: C12H24N2O3
Relative molecular mass: 244.0
CAS Number: 6425-39-4
Applications of DABCO DMDEE:
2,2-bismorpholinyl diethyl ether is suitable for water curing systems, A strong blowing catalyst, due to the steric hindrance of amino groups, can extend the storage period of NCO components, suitable for the catalytic reaction of NCO and water in systems such as TDI, MDI, and IPDI; 2,2-Bismorpholinyl diethyl ether is mainly used in one-component rigid polyurethane foam systems, and can also be used in polyether and polyester polyurethane soft foams, semi-rigid foams, CASE materials, etc.
DABCO DMDEE accounts for 0.3-0.55% of the polyether/ester component.
Bismorpholinyl diethyl ether is an amine catalyst suitable for curing systems.
DABCO DMDEE is a strong blowing catalyst. Due to the steric hindrance of the amino group, the NCO-containing components have a long storage period.
DABCO DMDEE is mainly used in one-component rigid polyurethane foam system, and also used in polyether and polyester polyurethane soft foam, semi-rigid foam, CASE material, etc.
Product Type: Crosslinking Catalysts / Accelerators / Initiators > Amine or Nitrogen Content
2,2’-Dimorpholinodiethyl ether (DABCO DMDEE) is a specialty amine catalyst used in the production of flexible foam, high-resilient (HR) molded foam, and in coatings and adhesives
DABCO DMDEE catalyst is a high boilng catalyst for use in flexible polyester-based foams, semiflexible foams and HR moulded foams.
DABCO DMDEE catalyst can be used in one component moisture- cured system to provide a stable prepolymer that can undergo rapid cure.
DABCO DMDEE is also used as a catalyst in polyurethane insulating foams released under pressure or from pressurized cans, in hot melt urethane adhesives, in the formation of flexible orthopedic casts, and in warm melt adhesives used in book binding applications.
Category: Amines and Catalysts
Dimorpholinodiethylether ("DABCO DMDEE") is widely used in one component moisture cured systems.
These systems are isocyanate prepolymers that contain a catalyst, e.g., DABCO DMDEE.
DABCO DMDEE catalyzes the water-isocyanate reaction of the prepolymers upon exposure to water, e.g., moisture in the air or added water.
However, to provide adequate shelf life, the catalyst must provide good isocyanate stability to avoid side reactions which gel and harden the prepolymer prematurely.
These side reactions are generally branching reactions resulting in biuret and allophanate formation and some formation of isocyanate trimer.
Isocyanate stability can be tested by adding a catalyst to toluene diisocyanate and observing the formation of solids
DABCO DMDEE is a tertiary amine catalyst for the production of polyurethane foam, especially suitable for the manufacturing of polyester polyurethane foams or for the preparation of one component foams (OCF)
DABCO DMDEE is a 2,2’-dimorpholinodiethylether amine.
DABCO DMDEE acts as a very selective blowing catalyst.
DABCO DMDEE provides a stable prepolymer system.
DABCO DMDEE is excellent for one-component systems.
Used in adhesives.
DABCO DMDEE catalyst is a high-boiling amine that can be used in flexible polyester foams, HR moldedfoams, and moisture-cured foams and coatings.
DABCO DMDEE catalyst is a good blowing catalyst that does not cause cross-linking.
When used in moisture-cured systems, it provides a stable prepolymer with a rapid cure.
DABCO DMDEE can also be used in flexible polyester-based urethane foams, as well as semiflexible foams and HR molded foams.
DABCO DMDEE is an amine blowing catalyst.
DABCO DMDEE is used in rigid foam sealant systems as well as for flexible slabstock foams.
DABCO DMDEE is suitable for processing by extrusion blow molding.
DABCO DMDEE is an amine catalyst that is isocyanate stable.
DABCO DMDEE is used in one component moisture cured applications in CASE.
DABCO DMDEE is a highly selective blowing catalyst and mainly used in one component applications, like 1-K Spray foam or 1-K Adhesives.
Due to the specific structure the nitrogen is sterically hindered by the morpholine ring the reaction of polyol with isocyanate as well as other side reactions are hardly activated.
DABCO DMDEE, Dimorpholinodiethylether is a polyurethane catalyst.
Dimorpholinodiethylether is a strong blowing catalyst with low gelling activity.
Therefore, Dimorpholinodiethylether is a preferred catalyst for one-component polyurethane systems (OCF and prepolymers) with long shelf life.
DABCO DMDEE: 2,2’-dimorpholinildiethylether
Cas No:6425-39-4
Similar Products : DABCO DABCO DMDEE, JEFFCAT DABCO DMDEE, PCCAT DABCO DMDEE, RC Catalyst 6135
Morpholine diethyl ether is used as a catalyst (or curing agent) in single-component polyurethane systems (such as polyurethane single-component caulking agent, polyurethane single-component foam rubber, polyurethane single-component grouting material, etc.).
Since the one-component polyurethane prepolymer requires long-term storage stability, bismorpholine diethyl ether plays a key role in the stability and polymerization of the polyurethane prepolymer, which is also important for the bismorpholine diethyl ether Product quality puts forward extremely high requirements.
DABCO DMDEE is an amine blowing catalyst particularly suitable for one- and two-component rigid foam sealant systems as well as flexible slabstock foams.
DABCO DMDEE provides system tability in moisture cured polyurethane
DABCO DMDEE can be used in one- and two-component sealant foams as well as flexible slabstock foams.
Typical Properties of DABCO DMDEE:
Color: Amber
Flash point, PMCC, °C (°F): 166 (330)
Freezing point, °C :-28
Initial Boiling point, °C: 309
pH: 10.3
Specific gravity, 20/20°C : 1.06
Vapor pressure, mm Hg, 20°C : < 1
Viscosity, cSt, 15.5°C (60°F) : 29
VOC Content, %, by ASTM D 2369 : 76
Water solubility, % : > 10
Physical Properties of DABCO DMDEE:
Appearance clear, yellowish liquid with typical amine odor
Purity ≥ 99 %
Water Content ≤ 0.5 %
HANDLING AND STORAGE OF DABCO DMDEE:
DABCO DMDEE catalyst is a high-quality amine product which performs in urethane formulations when properly stored and handled.
Please refer to our bulletin on “Storage and Handling of Catalysts” and the Safety DatanSheet on this product for necessary information.
MOISTURE CURE ELASTOMERS OF DABCO DMDEE:
Moisture cure elastomers are finding increased use applications as adhesives, glues, hard set polymers and coatings.
These systems are typically single component and require excellent stability of the amine catalyst with the isocyanate
DABCO DMDEE is a weak catalyst for polyurethane formulations.
Due to the specific structure DABCO DMDEE is a very selective catalyst.
As the nitrogen is stericallyhindered by the morpholine ring the reaction of polyol with isocyanate as well as other sidereactions are hardly activated.
On the other hand the nitrogen-ethylether structural unit highlyactivates the water/isocyanate reaction.
Based on this selectivity DABCO DMDEE is the first choice for moisture cured one-component formulations.
Even when used in relatively high amounts it does not affect the shelf life time of the final product in respect to viscosity increase or curing rate.
It is recommended to use DABCO DMDEE for moisture cured adhesive, sealants aswell as for foams.
Additionally, DABCO DMDEE can be used as a weak, but veryselective catalyst for two component polyurethane foams.
Recommended Dosage of DABCO DMDEE:
The dosage has to be adjusted to the formulation to reachthe required reaction profile.
Usually dosage levels of DABCO DMDEE are in the range of 0,5 to 2,5 php (parts on100 parts polyol).
Product Safety and Handling of DABCO DMDEE:
DABCO DMDEE is an amine and has a slightly basic character.
Avoid contact witheyes or skin.
Security of DABCO DMDEE:
Dimorpholinyl diethyl ether can burn eyes and skin.
Once contact with eyes, wash eyes with plenty of water and seek medical treatment immediately.
In case of contact with the skin, rinse the affected area with water immediately.
In the process of material handling, it is advisable to wear goggles to prevent splashing, and it is advisable to wear butyl rubber gloves, rubber lab coats and rubber boots.
SYNONYMS:
Morpholine, 4,4`-(oxydi-2,1-ethanediyl)bis-
2,2`-Dimorpholinodiethyl ether
Registration dossier
2,2`-Dimorpholinyldiethyl ether
2,2`-dimorpholinyldiethyl ether
2,2`-dimorpholinyldiethyl ether
2,2`dimorpholinodiethylether
2,2-dimorfolin dietiletere
2,2-Dimorpholinodiethylether
4,4`-(oxydiethane-2,1-diyl)dimorpholine
4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine
4-{2-[2-(morpholin-4-yl)ethoxy]ethyl}morpholine
DABCO DMDEE
Trade names
DABCO DMDEE(2,2’-DIMORPHOLINODIETHYLETHER)