EMULSOGEN EL 360

CAS Number: 61791-12-6
Chemical name Castor oil based ethoxylate, 36 mol EO
INCI Name: PEG-36 Castor Oil

Emulsogen EL products are standard NPE-free emulsifiers in various EC formulations. 
Emulsogen EL 360 show excellent emulsification characteristics for many solvents and are not eye-irritating.
Emulsogen EL 360 is 100% bio-based with a fully segregated supply chain and a Renewable Carbon Index (RCI) of 100%.

Benefits of Emulsogen EL 360:
-Widely used in numerous registered formulations
-Reliable performance
-Target the green formulation market
-Improved formulation labeling
-Sustainable formulations
-Globally applicable
-Constant formulation properties
-Improved toxicological profile

Applications of Emulsogen EL 360:
-Crop protection
-Emulsifiable concentrate
-Suspo emulsion
-Emulsion in water
Oil dispersion
-Wetting

Emulsifier combinations of nonionic and anionic surfactants are used successfully for making up a number of biocides in the form of self-emulsifying, liquid concentrates. 
Combinations are more adaptable than individual emulsifiers and therefore ultimately also more economical.
Emulsogen EL 360 is a nonionic component which,when used in combination with anionic components such as Phenylsulfonat CA, CAL, is particularly suitable for emulsifying biocides based on the active ingredients of thiophosphoric acid esters such as ethyl parathion, methyl parathion, malathion, fenitrothion and so on. 
However, Emulsogen EL 360 is also suitable for herbicide active ingredients based on 2,4-D esters and 2,4,5-T esters and insecticide active ingredients from the chlorinated hydrocarbons group, such as toxaphene and chlordan.
Emulsogen EL 360 is always advisable to tailor the combination of Emulsogen EL 360 and the anionic components mentioned above to the active ingredients, solvents and concentrations used and make it as effective as possible

Emulsogen EL 360 is standard NPE-free emulsifier in various EC formulations. 

KEYWORDS:
61791-12-6, Castor oil based ethoxylate 36 mol EO, PEG-36 Castor Oil, Emulsogen EL 400, Emulsogen EL 360 A, Emulsogen EL 50, Emulsogen EL 200, Emulsogen EL 300, Emulsogen EL 360 LM, Emulsogen EL

Chemical Name of Emulsogen EL 360:
-castor oil based ethoxylate, 36 mol EO 

Product Function:
-Nonionic emulsifier

Chemical Type:
-Castor oil ethoxylates

Appearance (25°C): Viscous liquid
Active content: 100 %  
Water content: Max 0.5 % 
pH value: 7.0 - 8.5  
HLB About: 13.5 

Uses of Emulsogen EL 360:
EMULSOGEN EL 360 is a nonionic, standard NPE-free emulsifier.

Application and characetristics of Emulsogen EL 360:
Emulsogen EL 360 shows excellent emulsification characteristics for many solvents typically used in agrochemical formulations. 
Besides that, Emulsogen EL 360 is an environmentally friendly and not eye-irritating product.
Emulsogen EL 360 could be used to achieve the following crop protection formulation types: Emulsifiable Concentrate [EC], Emulsion in Water [EW], Suspension Concentrate [SC], Suspoemulsion [SE] and Oil Dispersion [OD].
Emulsogen EL 360 is often used in combination with anionic emulsifier components such as Phenylsulfonat CA and Phenylsulfonat CAL and other non-ionic emulsifiers as EO-PO block copolymers (EMULSOGEN 3510, EMULSOGEN EP 4901) and EMULSOGEN TS types.

CAS Number: 61791-12-6
Grade: Technical
Estimated Shipping Time: Ships in 1-2 Business Days
Appearance: liquid
Color: yellow
Density: 1.04 g/cm3 @ 50.00 °C (122.00 °F)
Dynamic Viscosity: 400 mPa.s @ 21.11 °C (70.00 °F)
Flash Point: > 260.00 °C (> 500.00 °F)
Freezing Point: < 61 °C (< 142 °F)
Odor: fatty odour
pH: 7.0 - 9.0
Recommended Use: Textile auxiliary
Solubility in Water: soluble
Concentration [%]: at least 99
Ionicity: nonionic

Compatibility of Emulsogen EL 360:
Emulsogen EL 360 is miscible with the standard solvents used for Agrochemical formulations, including vegetable oils and its esters, aromatic solvents, mineral oil, N-alkyl-pyrrolidones, N,N-dimethyl-alkanamides among others.

Typical Use Level of Emulsogen EL 360:
As for standard emulsifiers and emulsifier packages, typical rates are around 5 to 15 % with respect to the oil phase. 
Mixing Emulsogen EL 360 with other emulsifiers might allow to reduce the use level and increase emulsion stability.

Storage and Handling of Emulsogen EL 360:
Emulsogen EL 360 can be stored in the original containers tightly closed in a cool, well-ventilated place.
In case of using only part of the container, homogenise the content before product withdrawal.

Safety of Emulsogen EL 360:
Further information on handling, storage and dispatch is given in the material safety data sheet.

Chemical Name: PEG-36 Castor Oil 
Product Function: Nonionic emulsifier
Chemical Type: Castor oil ethoxylates
Applications: Crop protection

Methode of Emulsogen EL 360:
Emulsogen EL 360 dissolves in the solvents normally use in the manufacture of biocides, forming a clear solution. 
Emulsogen EL 360 can therefore be stirred at room temperature, together with the appropriate anionic component, straight into the active ingredient solution. 
If necessary Emulsogen EL 360 should be slightly heated. 
At any rate the finished concentrate must be completely homogeneous and absolutely clear. 
Emulsogen EL 360 must neither form layers nor separate.

When the concentrate is stirred into water spontaneous dispersion occurs. 
The corresponding emulsions have very good stability. 
The hardness of the water can vary from 0-900 ppm.
In addition to Emulsogen EL 360, Clariant also markets a slightly more hydrophilic emulsifier component known as Emulsogen EL 400.

Appearance : viscous liquid
Colour : yellow
Odour : characteristic
pH : approx. 7 (20 °C)
Concentration: 10 g/l
pour point : approx. 10 °C
Method: ISO 3016
Boiling point : > 250 °C
Flash point : approx. 340 °C
Upper explosion limit / upper flammability limit : Not applicable
Lower explosion limit / Lower flammability limit : Not applicable
Vapour pressure : < 0,1 hPa (20 °C)
Method: calculated
Relative vapour density : no data available
Density : 1,05 g/cm3 (20 °C)
Method: DIN 51757
1,04 g/cm3 (40 °C)
Method: DIN 51757
1,01 g/cm3 (80 °C)
Method: DIN 51757
Solubility(ies):
Water solubility : soluble (20 °C)

Product properties of Emulsogen EL 360:
Appearance at 20°C: Yellowish, viscous, pourable paste

Chemical / Physical Data of Emulsogen EL 360:
pH-value [1 % aqueous solution]: 7.0 – 8.5
Flashpoint [°C; Cleveland, DIN 51376 ]: approx. 300
Density [g cm-3; 50°C]: approx. 1.03
Water content [%; K.F.; DIN 51777]: max. 1

Guide formulations of Emulsogen EL 360:
Ethylparathion:
50.0 % ethyl parathion
45.0 % xylene
2.5 % Emulsogen EL 360
2.5 % Phenylsulfonat CA
50.0 % ethyl parathion
45.0 % aromatic solvents*
2.6 % Emulsogen EL 360
2.4. % Phenylsulfonat CA

Malathion:
50.0 % malathion
43.0 % xylene
3.6 % Emulsogen EL 360
3.4 % Phenylsulfonat CA
50.0 % malathion
45.0 % aromatic solvents
2.7 % Emulsogen EL 360
2.3 % Phenylsulfonat CA

Methylparathion:
50.0 % methyl parathion
43.0 % xylene
4.5 % Emulsogen EL 360
2.5 % Phenylsulfonat CA

60.0 % methyl parathion
33.0 % aromatic solvents
4.5 % Emulsogen EL 360
2.5 % Phenylsulfonat CA

60.0 % methyl parathion
33.0 % solvent naphtha
4.3 % Emulsogen EL 360
2.7 % Phenylsulfonat CA

70.0 % methyl parathion
20.0 % xylene
6.0 % Emulsogen EL 360
4.0 % Phenylsulfonat CA

Toxaphene:
50.0 % toxaphene, 90 %
45.0 % petroleum ether
2.6 % Emulsogen EL 360
2.4 % Phenylsulfonat CA

50.0 % toxaphene, 90 %
45.0 % xylene
2.9 % Emulsogen EL 360
2.1 % Phenylsulfonat CA

2,4-D-isooctyl ester:
60.0 % 2,4-D-isooctyl ester
34.0 % xylene
3.1 % Emulsogen EL 360
2.9 % Phenylsulfonat CA

60.0 % 2,4-D-isooctyl ester
35.0 % petroleum ether
2.8 % Emulsogen EL 360
2.2 % Phenylsulfonat CA

2,4,5-T-isooctyl ester:
60.0 % 2,4,5-T-isooctyl ester
35.0 % xylene
3.0 % Emulsogen EL 360
2.0 % Phenylsulfonat CA

60.0 % 2,4,5-T-isooctyl ester:
35.0 % petroleum ether
2.7 % Emulsogen EL 360
2.3 % Phenylsulfonat CA

Solubility of Emulsogen EL 360:
Emulsogen EL 360 dissolves to form a clear solution in water, xylene, solvent naphtha, aromatic solvents and petroleum ether

Hardness stability of Emulsogen EL 360:
Unaffected by the hardness constituents of water

FIRST AID MEASURES of Emulsogen EL 360:
General advice : Remove/ Take off immediately all contaminated clothing.
If inhaled : If inhaled, remove to fresh air.
Get medical advice/ attention.
In case of skin contact : In case of contact, immediately flush skin with plenty of water.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
If swallowed : Get medical attention immediately.

FIRE-FIGHTING MEASURES of Emulsogen EL 360:
Suitable extinguishing media : Water spray jet
Foam
Carbon dioxide (CO2)
Dry powder

Specific hazards during firefighting : In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Specific extinguishing methods : Wear suitable protective equipment.
Special protective equipment for firefighters : Self-contained breathing apparatus

ACCIDENTAL RELEASE MEASURES of Emulsogen EL 360:
Personal precautions, protective equipment and emergency procedures : Wear suitable protective equipment.
Environmental precautions : Do not allow to enter drains or waterways
Methods and materials for containment and cleaning up : Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water

HANDLING AND STORAGE of Emulsogen EL 360:
Advice on protection against fire and explosion : Observe the general rules of industrial fire protection
Advice on safe handling : No special measures necessary if stored and handled as prescribed.
Further information on storage conditions : Keep container tightly closed and in a well-ventilated place.

Personal protective equipment
Respiratory protection : not required under normal use
Use only in well-ventilated areas.

Hand protection of Emulsogen EL 360:
Break through time : 480 min
Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves
Break through time : 30 min
Glove thickness : 0,4 mm
For short-term exposure (splash protection): Nitrile rubber gloves.
These types of protective gloves are offered by various manufacturers. 
Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. 
Consider also the particular working conditions under which the gloves are being used.

Eye protection : Safety glasses
Protective measures : Avoid contact with skin and eyes.
Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it before reuse.

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