POLYQUATERNIUM 46

LUVIQUAT HOLD

CAS Number: 174761-16-1
Molecular Formula: C21H34N4O6S

Polyquaternium is the International Nomenclature for Cosmetic Ingredients designation for several polycationic polymers that are used in the personal care industry. 
Polyquaternium is a neologism used to emphasize the presence of quaternary ammonium centers in the polymer. 

INCI has approved at least 40 different polymers under the polyquaternium designation. 
Different polymers are distinguished by the numerical value that follows the word "polyquaternium". 

Polyquaternium-5, polyquaternium-7, and polyquaternium-46 are three examples, each a chemically different type of polymer. 
The numbers are assigned in the order in which they are registered rather than because of their chemical structure.
 
Polyquaterniums find particular application in conditioners, shampoo, hair mousse, hair spray, hair dye, personal lubricant, and contact lens solutions. 
Because they are positively charged, they neutralize the negative charges of most shampoos and hair proteins and help hair lie flat. 

Their positive charges also ionically bond them to hair and skin. 
Some have antimicrobial properties.

Polyquaternium-46 is a polymeric quaternary ammonium salt prepared by the reaction of vinylcaprolactam and vinylpyrrolidone with methylvinylimidazolium methosulfate.

Polyquaternium-46 is present in 0.04% of cosmetics.

Polyquaternium-46 is a quaternized copolymer for hair and skin care. 
Polyquaternium-46 is an aqueous solution of cationic polymers of different charge density and different degrees of setting and conditioning. 

Polyquaternium-46 is a clear to slightly turbid yellowish viscous liquid, with a slight characteristic odor. 
Polyquaternium-46 has a weight composition of 40% VP, a solids content of 19-21, and a charge density of 0.5 meq/g at pH 7. 
Polyquaternium-46 is ideally used in mouse, gel spray, hair and skin conditioner and shampoo, body lotion, and shaving preparations.

Polyquaternium-46 is a rare cosmetic ingredient, with about 0.01% of the products in our database containing Polyquaternium-46.

Polymeric quaternary ammonium salt.
Reaction product of vinylcaprolactam, vinylpyrrolidone with methylvinylimidazolium methosulfate.

Action in cosmetics - a substance used in shampoos, conditioners and hair sprays has antistatic and softening properties, helps to straighten hair and prevent frizz.
The positive charge of the particles neutralizes the negative charge of the hair protein, thanks to which the hair is smooth, non-static and easy to comb.

By creating a protective layer, Polyquaternium-46 prevents skin and hair from drying out.
Makes hair shiny and silky soft to the touch. 
Polyquaternium-46 can also be used to modify foaming properties - Polyquaternium-46 reduces the size of air bubbles, improves foam stability and increases glide, thus creating a rich, creamy foam with excellent glide, which is important in, for example, shaving products.

Occurrence in cosmetics of Polyquaternium-46:
Nail care products, hair care products

The group of polyquaternium polymers includes a wide range of chemically different polymers, all of which carry a quaternary ammonium compound as a cationic functional group.
They are preferably used as film formers for hair and fingernails, but also as fixatives and antistatic agents in hair care products.

Functions of Polyquaternium-46:
Antistatic: Reduces static electricity by neutralizing the electrical charge on a surface

Film forming agent: Produces a continuous film on the skin, hair or nails

Hair fixing agent: Allows to control the style of the hair

Function in a cosmetic of Polyquaternium-46:
Conditioning substance
A consistency substance
Antistatic substance
Film-forming substance
Auxiliary substance
Hair fixative

Personal care products of Polyquaternium-46:
Film-forming agent, antistatic agent, hair fixing agent in personal care products.

Characteristics of Polyquaternium-46:
Excellent antistatic, emulsifying, dispersing, solubilizing, wetting, film-forming abilities.

Ecology of Polyquaternium-46:    
May be hazardous to environment. 
Water body should be given special attention.

Typical applications of Polyquaternium-46:
Use as antistatic agent.
Use as emulsifying agent, dispersing agent.
Use as flocculant.
Use as deodorant.
Use as film-forming agent.

Action in cosmetics of Polyquaternium-46:
The substance used in shampoos, conditioners and hair sprays has an antistatic and softening effect, helps to straighten hair and prevent frizz.
The positive charge of the particles neutralizes the negative charge of the hair protein, thanks to which the hair is smooth, non-static and easy to comb.

By creating a protective layer, Polyquaternium-46 prevents skin and hair from drying out.
Makes hair shiny and silky soft to the touch.
Polyquaternium-46 can also be used to modify foaming properties - Polyquaternium-46 reduces the size of air bubbles, improves foam stability and increases glide, thus creating a rich, creamy foam with excellent glide, which is important in, for example, shaving products.

Antistatic:
Reduces electrostatic charges (e.g. on the hair).

Film forming:
Forms a film on skin, hair or nails.

Hair Fixing:
Allows for durable shaping and styling of hairstyles.

Use Classification
Cosmetics - Antistatic
Film forming
Hair fixing

Warnings of Polyquaternium-46:
Polyquaternium-46 in skin and hair care products is considered safe and generally does not cause any irritation.
Polyquaternium-46 can be used in the daily care of both people with sensitive skin and children.

Properties of Polyquaternium-46:
Appearance: colorless to pale yellow liquid; or solid.
Solubility: soluble in water.
Stability: stable.

Polyquaternium-46 is a polymeric quaternary ammonium salt prepared by the reaction of vinylcaprolactam and vinylpyrrolidone with methylvinylimidazolium methosulfate.

KEYWORDS:
LUVIQUAT HOLD, 174761-16-1, Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9

Molecular Weight: 470.6
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 6
Rotatable Bond Count: 3
Exact Mass: 470.21990599
Monoisotopic Mass: 470.21990599
Topological Polar Surface Area: 124 Ų
Heavy Atom Count: 32
Complexity: 443
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 4
Compound Is Canonicalized: Yes

Origin(s): Synthetic
INCI name: POLYQUATERNIUM-46
Classification: Quaternary ammonium, synthetic polymer

POLYQUATERNIUM-46 is classified as:
Antistatic
Film forming
Hair fixing

Chem/IUPAC Name: Polyquaternium-46 is a polymeric quaternary ammonium salt prepared by the reaction of vinylcaprolactam and vinylpyrrolidone with methylvinylimidazolium methosulfate

Polyquaternium varieties:

Polyquaternium - Chemical Identity
Polyquaternium-1: Ethanol, 2,2′,2″ -nitrilotris-, polymer with 1,4-dichloro-2-butene and N,N,N′,N′-tetramethyl-2-butene-1,4-diamine
Polyquaternium-2: Poly[bis(2-chloroethyl) ether-alt-1,3-bis[3-(dimethylamino)propyl]urea]
Polyquaternium-4: Hydroxyethyl cellulose dimethyl diallylammonium chloride copolymer; Diallyldimethylammonium chloride-hydroxyethyl cellulose copolymer
Polyquaternium-5: Copolymer of acrylamide and quaternized dimethylammoniumethyl methacrylate
Polyquaternium-6: Poly(diallyldimethylammonium chloride)
Polyquaternium-7: Copolymer of acrylamide and diallyldimethylammonium chloride
Polyquaternium-8: Copolymer of methyl and stearyl dimethylaminoethyl ester of methacrylic acid, quaternized with dimethylsulphate[2]
Polyquaternium-9: Homopolymer of N,N-(dimethylamino)ethyl ester of methacrylic acid, quaternized with bromomethane
Polyquaternium-10: Quaternized hydroxyethyl cellulose
Polyquaternium-11: Copolymer of vinylpyrrolidone and quaternized dimethylaminoethyl methacrylate
Polyquaternium-12: Ethyl methacrylate / abietyl methacrylate / diethylaminoethyl methacrylate copolymer quaternized with dimethyl sulfate
Polyquaternium-13: Ethyl methacrylate / oleyl methacrylate / diethylaminoethyl methacrylate copolymer quaternized with dimethyl sulfate
Polyquaternium-14: Trimethylaminoethylmethacrylate homopolymer
Polyquaternium-15: Acrylamide-dimethylaminoethyl methacrylate methyl chloride copolymer
Polyquaternium-16: Copolymer of vinylpyrrolidone and quaternized vinylimidazole
Polyquaternium-17: Adipic acid, dimethylaminopropylamine and dichloroethylether copolymer
Polyquaternium-18: Azelaic acid, dimethylaminopropylamine and dichloroethylether copolymer
Polyquaternium-19: Copolymer of polyvinyl alcohol and 2,3-epoxypropylamine
Polyquaternium-20: Copolymer of polyvinyl octadecyl ether and 2,3-epoxypropylamine
Polyquaternium-22: Copolymer of acrylic acid and diallyldimethylammonium Chloride
Polyquaternium-24: Quaternary ammonium salt of hydroxyethyl cellulose reacted with a lauryl dimethyl ammonium substituted epoxide.
Polyquaternium-27: Block copolymer of Polyquaternium-2 and Polyquaternium-17
Polyquaternium-28: Copolymer of vinylpyrrolidone and methacrylamidopropyl trimethylammonium
Polyquaternium-29: Chitosan modified with propylen oxide and quaternized with epichlorhydrin
Polyquaternium-30: Ethanaminium, N-(carboxymethyl)-N,N-dimethyl-2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]-, inner salt, polymer with methyl 2-methyl-2-propenoate
Polyquaternium-31: N,N- dimethylaminopropyl-N-acrylamidine quatemized with diethylsulfate bound to a block of polyacrylonitrile
Polyquaternium-32: Poly(acrylamide 2-methacryloxyethyltrimethyl ammonium chloride)
Polyquaternium-33: Copolymer of trimethylaminoethylacrylate salt and acrylamide
Polyquaternium-34: Copolymer of 1,3-dibromopropane and N,N-diethyl-N′,N′-dimethyl-1,3-propanediamine
Polyquaternium-35: Methosulphate of the copolymer of methacryloyloxyethyltrimethylammonium and of methacryloyloxyethyldimethylacetylammonium
Polyquaternium-36: Copolymer of N,N-dimethylaminoethylmethacrylate and buthylmethacrylate, quaternized with dimethylsulphate
Polyquaternium-37: Poly(2-methacryloxyethyltrimethylammonium chloride)
Polyquaternium-39: Terpolymer of acrylic acid, acrylamide and diallyldimethylammonium Chloride
Polyquaternium-42: Poly[oxyethylene(dimethylimino)ethylene (dimethylimino)ethylene dichloride]
Polyquaternium-43: Copolymer of acrylamide, acrylamidopropyltrimonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine
Polyquaternium-44: 3-Methyl-1-vinylimidazolium methyl sulfate-N-vinylpyrrolidone copolymer
Polyquaternium-45: Copolymer of (N-methyl-N-ethoxyglycine)methacrylate and N,N-dimethylaminoethylmethacrylate, quaternized with dimethyl sulphate
Polyquaternium-46: Terpolymer of vinylcaprolactam, vinylpyrrolidone, and quaternized vinylimidazole
Polyquaternium-47: Terpolymer of acrylic acid, methacrylamidopropyl trimethylammonium chloride, and methyl acrylate

Synonyms of Polyquaternium-46:
1H-IMIDAZOLIUM
1-ETHENYL-3-METHYL-
METHYL SULFATE
POLYMER WITH 1-ETHENYLHEXAHYDRO-2H-AZEPIN-2-ONE
1-ETHENYL-2-PYRROLILDINONE
METHYL SULFATE POLYMER WITH 1-ETHENYLHEXAHYDRO-2H-AZEPIN-2-ONE 1H-IMIDAZOLIUM
1-ETHENYL-3-METHYL-
POLYMER WITH 1-ETHENYLHEXAHYDRO-2H-AZEPIN-2-ONE 1H-IMIDAZOLIUM
1-ETHENYL-3-METHYL-
METHYL SULFATE
POLYQUATERNIUM-46
1-ethenylazepan-2-one
1-ethenyl-3-methylimidazol-3-ium
1-ethenylpyrrolidin-2-one
methyl sulfate
polymeric quaternary ammonium salt prepared by the reaction of vinylcaprolactam and vinylpyrrolidone with methylvinylimidazolium methosulfate
Luviquat Hold
174761-16-1
LUVIQUAT (R) HOLD
1-ethenylazepan-2-one;1-ethenyl-3-methylimidazol-3-ium;1-ethenylpyrrolidin-2-one;methyl sulfate
Polyquaternium-46
DTXSID30169896

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